A special agitator shaft with symmetrically arranged agitator pegs and sleeves of tungsten carbide for wear protection devel- Vertical, batch operation mill for the preparation of tungsten Ideal flow behaviour due to a special agitator peg arrange-ment and the hemispherically shaped chamber floor integrated screen plate for grinding media separationIntensive cooling through a double-wall grinding tank and cooled circulation pipeline
Product inlet via rotor / immersion tube system prevents back flow of grinding media into the feed line.
Generally, there are two ways to obtain nano-powders. A bottom-up manufacturing method (bottom up) for chemical methods, such as chemical precipitation, sol-gel process (sol-gel),... Another method is physical method, which changes the powder particles from big to small (top down), such as mechanical ball milling,... And so on.
The Development In 1963, the first vertical agitator was developed internationally, the first horizontal agitator was developed in 1975, the first horizontal agitator bead mill with eccentric disks was introduced to the public and the horizontal disc grinder was introduced, in 2004, which became the industry standard. In the following years, the grinding media separation systems, the geometry of the grinding disks and the various grinding chamber materials were further developed.
The grinding system pin nanomill shows the evolutionary develop- ment of system with the rotor-slotted pipe separating system. The enclosed horizontal agitator mill is designed for highest product throughput rates and possesses a pin grinding system for highest grinding intensity.
In 2011, we developed the first zirconia comminution chamber technology in China. It has no metal ion pollution and is used in batteries, pharmaceuticals, glazes, ink and food.
(一)工作原理
磷酸鐵鋰電池,是指用磷酸鐵鋰作為正極材料的鋰離子電池。鋰離子電池的正極材料主要有鈷酸鋰、錳酸鋰、鎳酸鋰、三元材料、磷酸鐵鋰等。其中鈷酸鋰是目前絕大多數鋰離子電池使用的正極材料。
(二)意義
金屬交易市場,鈷(Co)最貴,并且存儲量不多,鎳(Ni)、錳(Mn)較便宜,而鐵(Fe)存儲量較多。正極材料的價格也與這些金屬的價格行情一致。因此,采用LiFePO4正極材料做成的鋰離子電池應是挺便宜的。它的另一個特點是對環境環保無污染。
(三)作為充電電池的要求是
容量高、輸出電壓高、良好的充放電循環性能、輸出電壓穩定、能大電流充放電、電化學穩定性能、使用中安全(不會因過充電、過放電及短路等操作不當而引起燃燒或爆炸)、工作溫度范圍寬、無毒或少毒、對環境無污染。采用LiFePO4作正極的磷酸鐵鋰電池在這些性能要求上都不錯,特別在大放電率放電(5~10C放電)、放電電壓平穩上、安全上(不燃燒、不爆炸)、壽命上(循環次數)、對環境無污染上,它是最好的,是目前最好的大電流輸出動力電池。
(四)結構與工作原理
LiFePO4作為電池的正極,由鋁箔與電池正極連接,中間是聚合物的隔膜,它把正極與負極隔開,但鋰離子Li可以通過而電子e-不能通過,右邊是由碳(石墨)組成的電池負極,由銅箔與電池的負極連接。
電池的上下端之間是電池的電解質,電池由金屬外殼密閉封裝。LiFePO4電池在充電時,正極中的鋰離子Li通過聚合物隔膜向負極遷移;在放電過程中,負極中的鋰離子Li通過隔膜向正極遷移。鋰離子電池就是因鋰離子在充放電時來回遷移而命名的。
(五)磷酸鐵鋰在生產過程中,其中的一步重要工藝需要用到砂磨機,目前主流砂磨機設備一般選擇棒銷式砂磨機,轉子加速器采用聚氨酯材料,研磨桶采用碳化硅陶瓷,經過粗磨,細磨兩步,達到D50=350-400納米的粒度分布水平。后續經過噴霧干燥進行下一步工藝。